阳极NiO/YSZ含量对SOFC电化学性能的影响The Influence of Anode Content of NiO/YSZ on Electrochemical Performance for SOFC
石纪军;程亮;罗凌虹;吴也凡;叶国友;
摘要(Abstract):
采用水系流延技术制备电解质,利用涂覆法分别在电解质面涂覆Ni O/YSZ阳极和LSM/YSZ阴极得到电解质支撑型单电池。采用SEM和电化学工作站等测试手段分别对半电池的结构和单电池的电性能进行表征。研究结果表明,经1500℃保温2h烧成电解质,经1250℃保温2 h烧成半电池,电解质表面致密,阳极与电解质结合性好。Ni O/YSZ=6∶4阳极的单电池以氢气+3%H2O为燃料气,空气为氧化气,在750℃运行的最大功率密度为0.20 W/cm2,极化阻抗为0.98Ω·cm2。
关键词(KeyWords): 阳极;电化学性能;Ni O/YSZ
基金项目(Foundation): 国家自然科学基金项目(编号:51262010,51462011);; 江西省主要学科学术和技术带头人培养计划项目(编号:20133BCB22009)
作者(Authors): 石纪军;程亮;罗凌虹;吴也凡;叶国友;
DOI: 10.13958/j.cnki.ztcg.2015.04.002
参考文献(References):
- [1]韩敏芳,彭苏萍.固体氧化物燃料电池材料及制备[M].北京:科学出版社,2004:2-8.
- [2]刘琪,张爱华,顾幸勇.固体氧化物燃料电池用Sc SZ粉体的研究进展[J].陶瓷学报,2013,34(4):538-542.
- [3]HABERKO K,JASINSKI M,PASIERB P,et al.Structural and electrical properties of Ni-YSZ cermet materials[J].Journal of Power Sources,2010,195(17):5527-5533.
- [4]HOLZER L,IWANSCHITZ B,HOCKER T,et al.Microstructure degradation of cermet anodes for solid oxide fuel cells:Quantification of nickel grain growth in dry and in humid atmospheres[J].Journal of Power Sources,2011,196:1279-1294.
- [5]刘琪,张爱华,顾幸勇.固体氧化物燃料电池用Sc SZ粉体的研究[J].中国陶瓷工业,2013,20(3):14-17.
- [6]PAN Weiping,LU Zhe,CHEN Kongfa,et al.Novel polymer fibers prepared by electrospinning for use as the pore-former for the anode of solid oxide fuel cell[J].Electrochimica Acta,2010,55:5538-5544.
- [7]MARRERO-LOPEZ D,RUIZ-MORALES J C,PENAMARTINEZ J,et al.Preparation of thin layer materials with macroporous microstructure for SOFC applications[J].Journal of Solid State Chemistry,2008,181:685-692.
- [8]LEE J H,HEO J W,LEE D S,et al.The impact of anode microstructure on the power generating characteristics of SOFC[J].Solid State Ionics.2003,158:225-232.
- [9]CAI Tongxiang,ZENG Yanwei,ZHANG Wei,et al.Synthesis of nanocomposite nickel oxide/yttrium-stabilized zirconia(Ni O/YSZ)powders for anodes of solid oxide fuel cells(SOFCs)via mcrowave-assisted complex-gel auto-combustion[J].J.Power Sources,2010,195(5):1308-1315.
- [10]余永志,罗凌虹,吴也凡,等.PMMA含量对水系流延ITSOFC性能的影响[J].中国陶瓷,2012,48(3):13-16.
- [11]文有强,刘宁,李凯,等.流延法制备8YSZ薄膜[J].陶瓷学报,2012,33(1):26-30.
- [12]薛纪溥,高文元.溶胶凝胶法合成La0.7Sr0.3Fe0.8Co0.2O3影响因素的研究[J].中国陶瓷工业,2014,21(3):14-17.
- [13]LIU Zhangbo,DING Dong,LIU Beibei,et al.Effect of impregnation phases on the performance of Ni-based anodes for low temperature solid oxide fuel cells[J].Journal of Power Sources,2011,196(20):8561-8567.
- [14]HEIDARPOUR A,SAIDI A,ABBASI M H,et al.In situ fabrication mechanism of a dense Sr and Ca doped lanthanum chromite interconnect on Ni-YSZ anode of a solid oxide fuel cell during co-sintering[J].Ceram.Int.,2013,39(2):1821-1826.
- [15]陈婷,王绍荣.固体氧化物电解池电解水研究综述[J].陶瓷学报,2014,35(1):1-6.
- [16]MORALES M,NAVARRO M E,CAPDEVILA X G,et al.Processing of graded anode-supported micro-tubular SOFCs based on samaria-doped ceria via gel-casting and spraycoating[J].Ceram.Int.,2012,38:3713-3722.
- [17]AI N,LV Z,TANG J K,et al.Improvement of output performance of solid oxide fuel cell by optimizing Ni/samariadoped ceria anode functional layer[J].J.Power Sources,2008,185:153-158.
- [18]LIU Y,LIU M.Porous SOFC anodes prepared by sublimation of an immiscible metal oxide during sintering[J].ECS.2006,9(5):234-245.
- [19]CRONIN J S,WILSON J R,BARNETT S A.Impact of pore microstructure evolution on polarization resistance of Niyttria-stabilized zirconia fuel cell anodes[J].Journal of Power Sources,2011,196:2640-2643.