卢秋杭;任凯彬;姜昊;马晓琛;任元文;夏泽林;刘世民;

• 1:大连交通大学材料科学与工程学院

摘要(Abstract)：

近些年来,能源开发利用对环境产生不同程度的不利影响,全球环境问题早已是亟待解决的现实和战略问题。农药、染料等对水的污染和有害气体对空气的污染日益加剧,而光催化反应可以降解这些污染物,且光催化在应用于抗菌、有机合成、能源开发等方面的作用毋庸置疑。本文对目前几种主要的光催化剂类型进行了归纳,同时综述了这些光催化剂的制备方法以及应用研究进展。

关键词(KeyWords)： 光催化反应;光催化剂;类型;制备;应用;综述

Abstract:

Keywords:

基金项目(Foundation): 辽宁省自然科学基金(2019-ZD-0096)

作者(Authors): 卢秋杭;任凯彬;姜昊;马晓琛;任元文;夏泽林;刘世民;

DOI: 10.13958/j.cnki.ztcg.2020.04.005

参考文献(References)：

• [1] Zhang, J. L, Ayusawa T, et al. Investigations of TiO2 photocatalysts for the decomposition of NO in the flow system:the role of pretreatment and reaction conditions in the photocatalytic efficiency[J]. Journal of Catalysts, 2001, 198(1):1-8.
• [2] K.Tennakone, K G U Wijayantha. Heavy-metal extraction from aqueous medium with an immobilized TiO2 photocatalyst and a solid sacrificial agent[J]. Journal of Photochemistry and Photobiology, 1998, 113(1):89-92.
• [3] Hu Chun, Wang Yizhong, Tang Hongxiao. Influence of adsorption on the photodegradation of various dyes using surface bond-conjugated Ti O2/Si O2 photocatalyst[J]. Applied catalysis B:Environmental, 2001, 35(2):95-105.
• [4] O Heintz, D Robert, J V Weber. Comparison of the degradation of benzamide and acetic acid on different TiO2 photocatalysts[J]. Journal of Photochemistry and Photobiology,2001, 35(1):77-78.
• [5] Deng Xingyi, Yue Yinghong, Gao Zi. Gas-phase photo-oxidation of organic compounds over nanosized Ti O2photocatalysts by various preparations[J]. Applied Catalysis,2002, 39(2):135-137.
• [6] Sang Bum Kim, Sung Chang Hong. Kinetic study for photocatalytic degradation of volatile organic compounds in air using thin film TiO2 photocatalyst[J]. Applied Catalysis B:Enviromental, 2002, 35(4):305-315.
• [7] C C Trapalis, P Keivanidis, et al. TiO2(Fe3+)nanostructured thin films with antibacterial properties[J]. Thin Solid Films,2003, 433(1-2):186-190.
• [8] S R Dhage, Renu Pasticha, V Ravi. Synthesis of ultrafine Ti O2 by citrate gel method[J]. Materials Reasearch Bulletin,2003, 38(11-12):1623-1628.
• [9] Dong-Seok Seo, Jong-Kook Lee, hwan Kim. Synthesis of Ti O2 nanocrystalline powder by aging at low temperature[J].Journal of Crystalgrowth, 2001, 233(1-2):298-302.
• [10] Yassine Bessekhouad, et al. Synthesis of photocatalytic TiO2nanoparticles:optimization of the preparation conditions[J].Journal of Photochemistry and Photobiology A:Chemistry,2003, 157(1):47-53.
• [11] GL Li, G H Wang. Synthesis of nanometer-sized TiO2 particles by a microemulsion method[J]. Nanostructure Materials,1999, 11(5):663-668.
• [12] M. Yoshida, K. Maeda, D. Lu, J. Kubota and K. Domen.Lanthanoid Oxide Layers on Rhodium-Loaded(Ga1–x Znx)(N1–x Ox)Photocatalyst as a Modifier for Overall Water Splitting under Visible-Light Irradiation[J]. J. Phys. Chem. C,2013, 117(27):14000-14006.
• [13] D. Dvoranova, V. Brezova, M. Mazur and M. Malati. Investigations of metal-doped titanium dioxide photocatalysts[J].Appl. Catal. B, 2002, 37(2):91-105.
• [14] H. G. Kim, P. H. Borse, W. Choi and J. S. Lee. Photocatalytic Nanodiodes for Visible-Light Photocatalysis[J]. Angew. Chem. Int. Ed, 2005, 44(29):4585-4589.
• [15] X. Wang, Q. Xu, M. Li, S. Shen, X. Wang, Y. Wang, Z.Feng, J. Shi, H. Han and C. Li. Photocatalytic Overall Water Splitting Promoted by anα–βphase Junction on Ga2O3[J].Angew. Chem. Int. Ed, 2012, 51(52):13089-13092.
• [16] S. S. Arbuj, U. P. Mulik and D. P. Amalnerkar. Synthesis of Ta2O5/Ti O2 Coupled Semiconductor Oxide Nanocomposites with High Photocatalytic Activity[J]. Nanosci. Nanotechnol.Lett, 2013, 5(9):968-973.
• [17] D. Barpuzary, Z. Khan, N. Vinothkumar, M. De and M.Qureshi. Hierarchically Grown Urchinlike CdS@ZnO and CdS@Al2O3 Heteroarrays for Efficient Visible-Light-Driven Photocatalytic Hydrogen Generation[J]. J. Phys. Chem. C,2012, 116(1):150-156.
• [18] L. Nasi, D. Calestani, T. Besagni, P. Ferro, F. Fabbri, F.Licci and R. Mosca. ZnS and ZnO Nanosheets from ZnS(en)0.5 Precursor:Nanoscale Structure and Photocatalytic Properties[J]. J. Phys. Chem. C, 2012, 116(12):6960-6965.
• [19] L. Mao, Y. Wang, Y. Zhong, J. Ning and Y. Hu. Microwave-assisted deposition of metal sulfide/oxidenanocrystals onto a 3D hierarchical flower-like Ti O2 nanostructure with improved photocatalytic activity[J]. J. Mater. Chem. A,2013, 1(28):8101-8104.
• [20] Jamuna K. Vaishnav, Sudhir S. Arbuj, Sunit B. Rane and Dinesh P. Amalnerkar. One dimensional Cd S/Zn O nanocomposites:an effiffifficient photocatalyst for hydrogen generation[J]. RSC Adv, 2014, 4(88):47637-47642.
• [21] X. Chen, S. S. Mao. Titanium Dioxide Nanomaterials:Synthesis, Properties, Modifications, and Applications[J].Chem. Rev, 2007, 107(7):2891-2959.
• [22] A. Testino, I. R. Bellobono, V. Buscaglia, et al. Optimizing the Photocatalytic Properties of Hydrothermal Ti O2 by the Control of Phase Composition and Particle Morphology. A Systematic Approach[J]. J. Am. Chem. Soc, 2007, 129(12):3564-3575.
• [23] J. L. West, N. J. Halas. Applications of nanotechnology to biotechnology:Commentary[J]. Curr. Opin. Biotechnol,2000, 11(2):215-217.
• [24] Y. N. Xia, P. D. Yang, Y. G. Sun, et al. One-Dimensional Nanostructures:Synthesis, Characterization, and Applications[J]. Adv. Mater, 2003, 15(5):353-389.
• [25] X. F. Gao, W. T. Sun, Z. D. Hu, et al. M. Peng. An Efficient Method To Form Heterojunction CdS/TiO2 Photoelectrodes Using Highly Ordered Ti O2 Nanotube Array Films[J]. J.Phys. Chem. C, 2009, 113(47):20481-20485.
• [26] H. Cui, K. Dwight, S. Soled, A. Wold. Surface Acidity and Photocatalytic Activity of Nb2O5/TiO2 Photocatalysts[J]. J.Solid State Chem, 1995, 115(1):187-191.
• [27] Z. Y. Liu, D. D. L. Sun, P. Guo, J. O. Leckie. An Efficient Bicomponent Ti O2/Sn O2 Nanofiber Photocatalyst Fabricated by Electrospinning with a Side-by-Side Dual Spinneret Method[J]. Nano Lett, 2007, 7(4):1081-1085.
• [28] Y. T. Kwon, K. Y. Song, W. I. Lee, et al. Photocatalytic Behavior of WO3-Loaded TiO2 in an Oxidation Reaction[J].J. Catal, 2000, 191(1):192-199.
• [29] C. Harris, P. V. Kamat. Photocatalysis with CdSe Nanoparticles in Confined Media:Mapping Charge Transfer Events in the Subpicosecond to Second Timescales[J]. ACS Nano,2009, 3(3):682-690.
• [30] Y. Yang, Y. B. Sun, Y. S. Jiang. Structure and photocatalytic property of perovskite and perovskite-related compounds[J].Mater. Chem. Phys, 2006, 96(2-3):234-239.
• [31] Y. Qin, G. Y. Wang, Y. J. Wang. Study on the photocatalytic property of La-doped Co O/Sr Ti O3 for water decomposition to hydrogen[J]. Catal. Commun, 2007, 8(6):926-930.
• [32] M. S. Wrighton, A. B. Ellis, P. T. Wolczanski, D. L. Morse,H. B. Abrahamson, D. S. Ginley. Strontium titanate photoelectrodes. Efficient photoassisted electrolysis of water at zero applied potential[J]. J. Am. Chem. Soc, 1976, 98(10):2774-2779.
• [33] Jiawei Ng, Shiping Xu, Xiwang Zhang, et al. Hybridized Nanowires and Cubes:A Novel Architecture of a Heterojunctioned TiO2/SrTiO3 Thin Flim for Efficient Water Splitting[J]. Adv. Funct. Mater, 2010, 20(24):4287-4294.
• [34] K Tennakone, K G U Wijayantha. Heavy-metal extraction from aqueous medium with an immobilized TiO2 photocatalyst and a solid sacrificial agent[J]. Journal of photochemistry and photobiology, 1998, 113(1):89-92.
• [35] B Tryba, A W Morawski, M Inagaki. Application of Ti O2-mounted activated carbon to the removal of phenol from water[J]. Applied catalysis B:Environmental, 2003,41(4):427-433.
• [36]吴跃辉,邓岩松,吴建辉.纳米Ti O2光催化剂在工业有机废水处理中的研究[J].江西化工, 2004(1):18-20.
• [37]申利春,李敏贤.纳米Ti O2光催化剂的制备与应用研究进展[J]. 2007, 30(8):12-15.
• [38] Zhang, Jinlong, Terukazu Ayusawa, et al. Investigations of Ti O2 photocatalysts for the decomposition of NO in the flow system:the role of pretreatment and reaction conditions in the photocatalytic efficiency[J]. Journal of Catalysts, 2001,198(1):1-8.
• [39] Tak-Hyoung lim, Sang, Mun Jeong, et al. Degradation Characteristics of NO by Photocatalysis with Ti O2 and CuO/TiO2[J]. React. Kinet. Catal. Lett, 2000, 71(2):223-229.
• [40]殷永泉,苏元成,由丽娜,等.复合催化剂对气相苯和甲苯的光催化降解研究[J].环境科学, 2007, 28(6):1188-1192.
• [41]张楠,张燕辉,潘晓阳,等.光催化选择性氧化还原体系在有机合成中的研究进展[J].中国科学：化学, 2011, 47(7):1097-1111.
• [42]臧丹炜,杨亚君.纳米Ti O2光催化剂的制备及应用[J].天津化工, 2009, 23(5):1-4.
• [43] Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238(5358):37-38.
• [44]顾修全,王波,陈凡,等.氧化亚铜在太阳能电池,光催化领域的研究进展[J].现代化工, 2012, 32(2):19-23.